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Lead/Leadframe
Corrosion
Lead
corrosion, as the name implies, refers to the corrosion of the lead
itself. Lead corrosion is often due to inadequate lead finish, the
presence of contaminants on the leads, and exposure of the leads to
excessive moisture. It can
be accelerated by higher temperatures and the presence of electrical
bias on the leads.
Leadframe corrosion refers
to the corrosion of any part of the leadframe. Although this mechanism
becomes more critical if it occurs on the silver-plated areas (die pad where
the die is set and the bonding fingers) of the leadframe, corrosion on
any part of the leadframe must be rejected because the contaminants in
the corroded area can easily spread in the presence of moisture.
The most frequently
encountered contaminants in fresh leadframes are chlorine, phosphorus, sulfur,
and potassium. Newly-delivered leadframes from suppliers must undergo strict incoming
quality screening for contaminants/foreign materials to minimize the
risk of internal corrosion in semiconductor products.
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Fig 3. SEM photos
of corroded areas on contaminated die pads of various leadframes |
Wire
Corrosion
Corrosion of
the bond wires within a package can also occur, gross cases of which can
lead to wire breaking or even total disintegration of the wire. This
mechanism is more commonly encountered in aluminum wires that have been
contaminated by chlorine, although rare cases involving gold wires have
also be observed.
In the case of gold wires, delaminated areas
around the wire can act as conduit of Cl-contaminated moisture that can
expose the entire length of the wire to Cl and make it vulnerable to
massive corrosion. Other contaminants that accelerate gold wire
corrosion include bromide, iodide, and cyanide ions.
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Fig 4. SEM photo
of a corroded aluminum wire and wedge bond |
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See Also:
Oxidation/Reduction Potential Values; Package
Failures; Die Failures;
Failure
Analysis; Basic FA
Flows;
Reliability Models
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