Dry Etching
In wafer
fabrication, etching refers to a process by which material is removed
from the wafer, i.e., either from the silicon substrate itself or from
any film or layer of material on the wafer. There are two major
types of etching: dry etching and wet etching.
Dry Etching
is an etching process that does not utilize any liquid chemicals or
etchants to remove materials from the wafer, generating only volatile
byproducts in the process. Dry etching may be accomplished by any of the
following: 1) through chemical
reactions that consume the material,
using chemically reactive gases or plasma;
2)
physical removal of the material, usually by momentum transfer;
or 3) a combination of both physical removal and chemical reactions.
Plasma
etching is an example of a purely chemical dry etching technique. On the
other hand,
physical
sputtering and ion beam milling are examples of purely physical dry
etching techniques. Lastly, reactive
ion etching is an example of dry etching that employs both physical and
chemical processes.
Like wet etching, dry
etching also follows the resist mask patterns on the wafer, i.e., it
only etches away materials that are not covered by mask material (and
are therefore exposed to its etching species), while leaving areas
covered by the masks almost (but not perfectly) intact. These
masks were deposited on the wafer by an earlier wafer fab step known as
'lithography.'
Plasma
etching,
a purely chemical dry etching technique,
basically consists of the following steps: 1) generation of
reactive species in a plasma; 2) diffusion of these species to the
surface of the material being etched; 3) adsorption of these species on
the surface; 4) occurrence of chemical reactions between the species and
the material being etched, forming volatile byproducts; 5) desorption of
the byproducts from the surface; and 6) diffusion of the desorbed
byproducts into the bulk of the gas.
Note that the
desorption
of the reaction byproducts from the surface of the material being plasma etched
is just as important as the occurrence of the chemical reactions that
consume the material. If such desorption fails to occur, then
etching can not take place even if the chemical reactions have been
completed. Thus, all the steps above must occur for the plasma
etching process to be successful.
The selectivity
of the species used in dry etching that employs chemical reactions is
very important.
Selectivity
refers to the ability of the reactive species to etch away only the
material intended for removal, while leaving all other materials intact.
In particular, the species used must not attack the mask material over
the material being etched as well as the material beneath it.
In general, the reactive species used in
dry chemical etching must be selected so that the following criteria are met:
1) high selectivity against etching the mask material over the layer
being etched; 2) high selectivity against etching the material under the
layer being etched; 3) high etch rate for the material being removed;
and 4) excellent etching uniformity. They should also allow a
safe, clean, and automation-ready etching process.
Another
important consideration in any etching process is its
anisotropy,
or property of etching in one direction only. A completely
anisotropic etching process that removes material in the vertical
direction only is very desirable, since it will follow the mask patterns
on the wafer very faithfully, leaving any material covered by mask
material basically untouched.
<Proceed to Page 2 - Physical Sputtering and
Reactive Ion Etching>
See Also:
Wet
Etching; Lithography/Etch;
Optical Lithography;
Electron Lithography
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